Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/62251
Title: New class of bright and highly stable chiral cyclen europium complexes for circularly polarized Luminescence applications
Authors: Dai, L
Lo, WS
Coates, ID
Pal, R
Law, GL 
Issue Date: 2016
Publisher: American Chemical Society
Source: Inorganic chemistry, 2016, v. 55, no. 17, p. 9065-9070 How to cite?
Journal: Inorganic chemistry 
Abstract: High glum values of +0.30 (ΔJ = 1, 591 nm, in DMSO) and -0.23 (ΔJ = 1, 589 nm, in H2O) were recorded in our series of newly designed macrocyclic europium(III) complexes. A sterically locking approach involving a bidentate chromophore is adopted to control the formation of one stereoisomer, giving rise to extreme rigidity, high stability, and high emission intensity. The combination of a chiral substituent on a macrocyclic chelate for lanthanide ions opens up new perspectives for the further development of circulary polarized luminescent chiral tags in optical and bioapplications.
URI: http://hdl.handle.net/10397/62251
ISSN: 0020-1669
DOI: 10.1021/acs.inorgchem.6b01546
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