Please use this identifier to cite or link to this item:
Title: Thermodynamic selectivity of functional agents on zeolite for sodium dodecyl sulfate sequestration
Authors: Leng, L
Wang, J
Qiu, X
Zhao, Y 
Yip, YW
Law, GL 
Shih, K
Zhou, Z
Lee, PH 
Keywords: Isothermal titration calorimetry (ITC)
Quantum chemistry simulation (QCS)
Issue Date: 2016
Publisher: Elsevier
Source: Journal of hazardous materials, 2016, v. 318, p. 41-47 How to cite?
Journal: Journal of hazardous materials 
Abstract: This study proposes a thermodynamic approach to effectively select functional agents onto zeolite for sodium dodecyl sulfate (SDS) sequestration in greywater reuse. We combine isothermal titration calorimetry (ITC) and quantum chemistry simulation (QCS) to identify the interactions between SDS and agents at the molecular level. Three potential agents, cetyl trimethyl ammonium bromide (CTAB), N,N,N-trimethyltetradecan-1-aminium bromide (C14TAB), and 14-hydroxy-N,N,N-trimethyltetradecan-1-aminium bromide (C14HTAB), differ in carbon chain length and hydrophilic groups. The ITC titration of SDS with CTAB released the highest heat, followed by those with C14TAB and C14HTAB, as was the same trend for the amounts of SDS adsorbed by the respective functionalized-zeolites. Results suggest that the favorable SDS sorption occurred at the bilayer CTAB-zeolite is driven by enthalpy as similar as the SDS…CTAB interaction found, regardless of the contribution from electrostatic and/or hydrophobic behaviors, while the declined sorption is entropy-driven via the predominant hydrophobic interaction onto the monolayer CTAB-zeolite. The data presented here interpret the nature of molecularly thermodynamic quantities and enable the manipulation of sorption capacity optimization.
ISSN: 0304-3894
EISSN: 1873-3336
DOI: 10.1016/j.jhazmat.2016.06.043
Appears in Collections:Journal/Magazine Article

View full-text via PolyU eLinks SFX Query
Show full item record

Page view(s)

Last Week
Last month
Citations as of Nov 12, 2018

Google ScholarTM



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.