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Title: Enhanced catalytic reduction of N-nitrosodimethylamine over bimetallic Pd-Ni catalysts
Authors: Chen, H
Li, T
Jiang, F
Wang, Z 
Keywords: Catalytic reduction
Metal dispersion
N-Nitrosodimethylamine (NDMA)
γ-Al2O3 supported bimetallic Pd-Ni catalysts
Issue Date: 2016
Publisher: Elsevier
Source: Journal of molecular catalysis A : chemical, 2016, v. 421, p. 167-177 How to cite?
Journal: Journal of molecular catalysis A : chemical 
Abstract: Catalytic reduction of N-nitrosodimethylamine (NDMA) was investigated over γ-Al2O3 supported bimetallic Pd-Ni catalysts (3%(PdxNi1-x)). NDMA could be reduced to dimethylamine over 3%(Pd0.8Ni0.2) with a metal-loading-normalized pseudo-first-order rate constant of 836 ± 21 L gme -1 h-1. Characterization results showed that the reducibility of PdO (or NiO) was improved by addition of Ni (or Pd) in 3%(PdxNi1-x); Pd-Ni ensembles were formed in 3%(PdxNi1-x) and there was an electronic transfer from Pd to Ni; metal dispersion was affected by the formation of Pd-Ni ensembles and a volcano curve of metal dispersion via Pd/Ni ratio was observed. The activity profiles demonstrated that TOF had a significant positive relationship with metal dispersion of 3%(PdxNi1-x), indicating high metal dispersion favor NDMA reduction. NDMA reduction over 3%(Pd0.8Ni0.2) catalyst could be described by Langmuir-Hinshelwood model, reflecting an adsorption controlled reduction mechanism. The reduction mechanism of NDMA over 3%(Pd0.8Ni0.2) catalyst was proposed to be that H2 was activated by Pd, and H spillover from Pd to Ni/NiO reduced NDMA though N-N cleavage.
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2016.05.026
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