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Title: Cracks bring robustness : a pre-cracked NiO nanosponge electrode with greatly enhanced cycle stability and rate performance
Authors: Zhang, G
Wang, L
Liu, Y
Li, W
Yu, F
Lu, W
Huang, H 
Issue Date: 2016
Publisher: Royal Society of Chemistry
Source: Journal of materials chemistry A, 2016, v. 4, no. 21, p. 8211-8218 How to cite?
Journal: Journal of materials chemistry A 
Abstract: The practical application of faradaic capacitors is hampered by electrodes' volume change in the charge/discharge process, which leads to the disintegration of the electrode structure and inferior long-term stability. It is desirable while challenging to develop a low cost and facile method to fabricate an electrode which can effectively accommodate volume expansion/contraction and alleviate the concomitant stress. Herein, taking NiO as an example, a promising route to solve the above issue is demonstrated by purposely introducing cracks in a NiO nanosponge through rapid thermal quenching. The NiO nanosponge is cracked into discrete islands with a size of several micrometers, with each unit strongly connected to a conductive nickel substrate. The small islands of NiO are capable of expanding/contracting freely during repeated charge/discharge processes, leading to a stable mechanical structure and excellent long-term durability. The pre-cracked NiO nanosponge outperforms many state-of-the-art Ni-based electrode materials, with a remarkable rate performance of 1546 F g-1 at 10 mV s-1 and 1109 F g-1 at 200 mV s-1 and no capacitance decay after 5000 cycles. The idea of relieving stress through thermally induced cracks is facile and effective. This will not only help the design of Ni-based electrode materials but also be extended to other transition metal compounds for the performance optimization.
ISSN: 2050-7488
EISSN: 2050-7496
DOI: 10.1039/c6ta02568d
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