Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/60501
Title: Biheteroaromatic diphosphines and their transition metal complexes : synthesis, characterisation and applications in asymmetric catalysis
Authors: Au-Yeung, TTL
Chan, ASC
Keywords: Biheteroaromatic diphosphines
Axial chirality
Asymmetric hydrogenation
Asymmetric 1,4-addition
Bis-alkoxycarbonylation
Asymmetric Heck reaction
Asymmetric Diels–Alder reaction
Issue Date: 2004
Publisher: Elsevier
Source: Coordination chemistry reviews, 2004, v. 248, no. 21-24, p. 2151-2164 How to cite?
Journal: Coordination chemistry reviews 
Abstract: Chelating diphosphines supported by biheteroaromatic compounds find increasing application in metal-catalyzed homogeneous catalysis. This review describes recent development in the synthesis and characterisation of atropisomeric biheteroaromatic diphosphines and some of their metal complexes by spectroscopic methods. The applications of the diphosphines in the asymmetric hydrogenation of α-, β-amino acid precursors and ketones, 1,4-arylation of enones, bis-alkoxycarbonylation, Heck reaction and Diels–Alder reaction are also discussed.
URI: http://hdl.handle.net/10397/60501
ISSN: 0010-8545
EISSN: 1873-3840
DOI: 10.1016/j.ccr.2004.08.026
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