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Title: | Thermally stimulated depolarization current of BaTiO₃/P[VDF(70)-TrFE(30)] 0-3 ferroelectric composites | Authors: | Zhang, X Peng, Z Chan, HLW Choy, CL |
Issue Date: | 1999 | Source: | ISE 10 : 10th International Symposium on Electrets : 22-24 September 1999, European Cultural Centre of Delphi, Greece : proceedings, p. 407-410 | Abstract: | 0-3 ferroelectric composites of barium titanate (BT) and vinylidene fluoride-trifluoroethylene copolymer P[VDF(70)-TrFE(30)] with different volume fraction of BT were prepared by solution blending followed by compression-molding. The thermally stimulated depolarization current (TSDC) of the composites has been measured. Three detrapping charge and two phase transition peaks (one for copolymer and another for ceramic) are observed in TSDC spectra above room temperature. For the composite sample in which only ceramic phase is polarized, the detrapping charge peaks are disappeared, which indicates that the TSDC originates from the copolymer phase. According to the analysis of phase transition, the structural origin of TSDC peaks is proposed. The detrapping charge density increases as increasing BT content, which shows that ceramic inclusions enhance the ability of charge storage in the composites. | Keywords: | Barium titanate Carrier concentration Compression molding Copolymers Electric space charge Ferroelectric materials Phase transitions Polarization Temperature Thick films Volume fraction Spectroscopy |
Publisher: | IEEE | ISBN: | 0-7803-5025-1 | Rights: | © 1999 IEEE. Personal use of this material is permitted. However, permission to reprint/republish this material for advertising or promotional purposes or for creating new collective works for resale or redistribution to servers or lists, or to reuse any copyrighted component of this work in other works must be obtained from the IEEE. This material is presented to ensure timely dissemination of scholarly and technical work. Copyright and all rights therein are retained by authors or by other copyright holders. All persons copying this information are expected to adhere to the terms and constraints invoked by each author's copyright. In most cases, these works may not be reposted without the explicit permission of the copyright holder. |
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