Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/55721
Title: Coupling reactions of CO2 with neat epoxides catalyzed by PPN salts to yield cyclic carbonates
Authors: Sit, WN
Ng, SM
Kwong, KY
Lau, CP
Issue Date: 2005
Publisher: American Chemical Society
Source: Journal of organic chemistry, 2005, v. 70 , no. 21, p. 8583-8586 How to cite?
Journal: Journal of organic chemistry 
Abstract: The off-the-shelf reagent PPN+Cl- and PPN-manganese carbonylates [PPN]+[Mn(CO)4L]- (L = CO, PPh3) are good catalysts for the coupling reactions of CO2 with neat epoxides without the use of organic solvents to afford cyclic carbonates. PPN salts with weak nucleophilic anions such as PPN +BF4 - and PPN+OTf- are, however, inactive for the coupling reactions.
URI: http://hdl.handle.net/10397/55721
ISSN: 0022-3263
EISSN: 1520-6904
DOI: 10.1021/jo051077e
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