Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/35783
Title: A general direct arylation of Polyfluoroarenes with Heteroaryl and Aryl Chlorides catalyzed by Palladium Indolylphosphine complexes
Authors: Yuen, OY
Charoensak, M
So, CM
Kuhakarn, C
Kwong, FY 
Keywords: Aryl chlorides
CH arylation
Palladium
Phosphine
Polyfluoroarenes
Issue Date: 2015
Publisher: Wiley-VCH
Source: Chemistry, an Asian journal, 2015, v. 10, no. 4, p. 857-861 How to cite?
Journal: Chemistry, an Asian journal 
Abstract: The first general examples of direct coupling of heteroaryl chlorides, especially substituted 2-pyridyl chlorides which were previously found to be problematic, with electron-deficient polyfluoroarenes are reported. Pd(OAc)(2) associated with 3-(dicyclohexylphosphino)-2-phenylindole L1 serves as the effective catalyst which allows the challenging direct coupling of heteroaryl chlorides and polyfluoroarenes. In addition to heterocycles, a wide range of non-activated and activated aryl chlorides and alkenyl chlorides were also applicable under this catalyst system. A catalyst loading down to 1mol% Pd can be achieved.
URI: http://hdl.handle.net/10397/35783
ISSN: 1861-4728 (print)
1861-471X (online)
DOI: 10.1002/asia.201500048
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