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Title: Chiral aminophosphine phosphinite – palladium catalysts in asymmetric allylic alkylations
Authors: Gong, L
Chen, G
Mi, A
Jiang, Y
Fu, F
Cui, X
Chan, AS
Issue Date: 2000
Publisher: Elsevier
Source: Tetrahedron : asymmetry, 2000, v. 11, no. 21, p. 4297-4302 How to cite?
Journal: Tetrahedron : asymmetry
Abstract: Palladium complexes of chiral aminophosphine phosphinites were investigated for the asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. The chirality of the carbon bonded to O-PPh2 in the ligands was found to be very important to the enantioselectivity of the catalysts. Introduction of this stereogenic center has led to significantly improved enantioselectivities.
ISSN: 0957-4166
DOI: 10.1016/S0957-4166(00)00412-2
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