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|Title:||Chiral aminophosphine phosphinite – palladium catalysts in asymmetric allylic alkylations|
|Source:||Tetrahedron : asymmetry, 2000, v. 11, no. 21, p. 4297-4302 How to cite?|
|Journal:||Tetrahedron : asymmetry|
|Abstract:||Palladium complexes of chiral aminophosphine phosphinites were investigated for the asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. The chirality of the carbon bonded to O-PPh2 in the ligands was found to be very important to the enantioselectivity of the catalysts. Introduction of this stereogenic center has led to significantly improved enantioselectivities.|
|Appears in Collections:||Journal/Magazine Article|
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