Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/34514
Title: Presence of high nitryl chloride in Asian coastal environment and its impact on atmospheric photochemistry
Authors: Tham, YJ
Yan, C
Xue, L
Zha, Q
Wang, X
Wang, T 
Keywords: Nitryl chloride
Chemical ionization mass spectrometer
Cl atom
Atmospheric photochemistry
Issue Date: 2014
Publisher: Springer
Source: Chinese science bulletin, 2014, v. 59, no. 4, p. 356-359 How to cite?
Journal: Chinese science bulletin
Abstract: Nitryl chloride (ClNO2) is a product of nocturnal halogen activation of nitrogen oxides and has potential to impact atmospheric photochemistry. Here we report the first observation result of ClNO2 in an Asian environment. The measurements were made with a thermal decomposition chemical ionization mass spectrometer at a coastal site in southern China during late summer of 2012. A clear diurnal pattern of ClNO2 was observed with nighttime 1-min average mixing ratio up to 1997 pptv, which is among the highest values ever reported in the world. The elevated ClNO2 mixing ratios were observed in plumes from Hong Kong and the Pearl River Delta region compared to the lower levels in maritime air. Calculations suggest that the production of chlorine atom from photolysis of ClNO2 in the early morning exceeds the production of hydroxyl radical via ozone photolysis by several factors. Therefore, ClNO2 plays an important role in jump-starting the atmospheric photochemistry in polluted marine boundary layer of southern China.
URI: http://hdl.handle.net/10397/34514
ISSN: 1001-6538 (print)
1861-9541 (electronic)
DOI: 10.1007/s11434-013-0063-y
Appears in Collections:Journal/Magazine Article

Access
View full-text via PolyU eLinks SFX Query
Show full item record

WEB OF SCIENCETM
Citations

11
Last Week
0
Last month
Citations as of Jan 22, 2017

Page view(s)

15
Last Week
0
Last month
Checked on Jan 22, 2017

Google ScholarTM

Check

Altmetric



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.