Please use this identifier to cite or link to this item:
Title: Study of the crystal structure of oxo-bridged binuclear FeIII complex with chiral salen ligand
Authors: Liu, T
Liu, QX
Ruan, WJ
Zhu, ZA
Chen, YT
Chan, ASC
Keywords: Chiral salen ligand
Crystal structure
Oxo-bridged binuclear FeIII complex
Issue Date: 2001
Source: Chinese journal of chemistry, 2001, v. 19, no. 4, p. 352-355 How to cite?
Journal: Chinese Journal of Chemistry 
Abstract: A oxo-bridged binuclear iron complex with chiral salen ligand [Fe2L2]O (H2L = R, R′-N, N′-bis(3, 5-di-tert-butylsalicylaldene)-1, 2-cyclohexanediamine) has been synthesized and the structure has been determined by X-ray diffraction analysis. The title complex crystallizes in triclinic system with space group P-1. Crystal data: a = 1.42555(14) nm, b = 1.54889 (15) nm, c = 1.83662(17) nm, α = 103.873 (2)°, β = 100.506(2)°, γ= 101.840(2)°, V = 3.7371 nm3, Dc = 1.082 g/cm3 and Z = 2. In the complex, each iron center is pentacoordination and in distorted square-pyramidal environment. Two FeIII atoms are intramolecularly bridged by an oxygen atom with Fe⋯Fe nonbond distance of 0.3517(3) nm.
ISSN: 1001-604X
Appears in Collections:Journal/Magazine Article

View full-text via PolyU eLinks SFX Query
Show full item record


Last Week
Last month
Citations as of Aug 16, 2018

Page view(s)

Last Week
Last month
Citations as of Aug 13, 2018

Google ScholarTM


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.