Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/33462
Title: Study of the crystal structure of oxo-bridged binuclear FeIII complex with chiral salen ligand
Authors: Liu, T
Liu, QX
Ruan, WJ
Zhu, ZA
Chen, YT
Chan, ASC
Keywords: Chiral salen ligand
Crystal structure
Oxo-bridged binuclear FeIII complex
Issue Date: 2001
Source: Chinese journal of chemistry, 2001, v. 19, no. 4, p. 352-355 How to cite?
Journal: Chinese Journal of Chemistry 
Abstract: A oxo-bridged binuclear iron complex with chiral salen ligand [Fe2L2]O (H2L = R, R′-N, N′-bis(3, 5-di-tert-butylsalicylaldene)-1, 2-cyclohexanediamine) has been synthesized and the structure has been determined by X-ray diffraction analysis. The title complex crystallizes in triclinic system with space group P-1. Crystal data: a = 1.42555(14) nm, b = 1.54889 (15) nm, c = 1.83662(17) nm, α = 103.873 (2)°, β = 100.506(2)°, γ= 101.840(2)°, V = 3.7371 nm3, Dc = 1.082 g/cm3 and Z = 2. In the complex, each iron center is pentacoordination and in distorted square-pyramidal environment. Two FeIII atoms are intramolecularly bridged by an oxygen atom with Fe⋯Fe nonbond distance of 0.3517(3) nm.
URI: http://hdl.handle.net/10397/33462
ISSN: 1001-604X
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