Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/33352
Title: Asymmetric borane reduction of prochiral ketones catalyzed by phosphinamides prepared from L-serine
Authors: Li, KY
Zhou, ZH
Wang, LX
Zhao, GF
Choi, MCK
Zhou, QL
Tang, CC
Issue Date: 2003
Source: Heteroatom chemistry, 2003, v. 14, no. 3, p. 288-291
Abstract: Synthesis of several new chiral phosphinamide catalysts with a proximal hydroxyl group from L-serine was described. These compounds have been successfully used in the asymmetric catalytic borans, reduction of prochiral ketones. The optically active secondary alcohols were obtained with an enantiomeric excess (ee) up to 81% and excellent yields.
Publisher: John Wiley & Sons Inc
Journal: Heteroatom Chemistry 
ISSN: 1042-7163
DOI: 10.1002/hc.10145
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