Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/32888
Title: Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network
Authors: Wang, H
Szeto, L
Chan, WTK 
Yeung, HL
Wong, KL
Wong, WT 
Keywords: 1,2-bis(4-pyridyl)hydrazine
Coordination polymer
Hydrogen bond
Interpenetrating polymer
Metal organic framework
Microporous
Issue Date: 2012
Publisher: National Research Council Canada
Source: Canadian journal of chemistry, 2012, v. 90, no. 1, p. 100-107 How to cite?
Journal: Canadian journal of chemistry 
Abstract: Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell.
URI: http://hdl.handle.net/10397/32888
ISSN: 0008-4042
EISSN: 1480-3291
DOI: 10.1139/v11-132
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