Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/32210
Title: Catalytic asymmetric addition reactions leading to carbon-carbon bond formation : Phenyl and alkenyl transfer to aldehydes and alkynylation of α-imino esters
Authors: Ji, JX
Wu, J
Xu, L
Yip, CW
Lam, KH
Chan, ASC
Keywords: Alkenylation
Alkynylation
Asymmetric
Catalyst
Phenylation
Issue Date: 2006
Source: Pure and applied chemistry, 2006, v. 78, no. 2, p. 267-274 How to cite?
Journal: Pure and Applied Chemistry 
Abstract: Optically active tertiary aminonaphthol ligands were obtained by a new, convenient procedure and were found to catalyze the enantioselective alkenyl and phenyl transfer to aldehydes in high yields and excellent enantiomeric excesses (ee's). The catalytic asymmetric introduction of alkynyl functionality to α-amino acid derivatives was realized by the direct addition of terminal alkynes to α-imino ester in the presence of chiral copper(I) complex under mild reaction conditions.
URI: http://hdl.handle.net/10397/32210
ISSN: 0033-4545
DOI: 10.1351/pac200678020267
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