Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/31269
Title: Synthesis and reactions of chiral clusters containing an SRuCoMo core
Authors: Zhang, YH
Yuan, JC
Yin, YQ
Zhou, ZY
Chan, ASC
Issue Date: 2001
Publisher: Royal Soc Chemistry
Source: New journal of chemistry, 2001, v. 25, no. 7, p. 939-944 How to cite?
Journal: New Journal of Chemistry 
Abstract: In order to resolve tetrahedron-type chiral clusters, three chiral clusters containing a functionally substituted cyclopentadienyl ligand were prepared, and the reactions of functional substituents were investigated. The ester group was hard to hydrolyze while hydrazide can easily condense with the ketonic carbonyl on the cyclopenta- dienyl ring to form a cluster hydrazone. Two optically active auxiliaries have been attached to the chiral framework; however, the diastereoisomers cannot be separated by silica gel chromatography. Their presence was established by C-13 NMR spectra.
URI: http://hdl.handle.net/10397/31269
ISSN: 1144-0546
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