Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/30862
DC FieldValueLanguage
dc.contributorDepartment of Applied Biology and Chemical Technology-
dc.creatorChan, SH-
dc.creatorLam, KH-
dc.creatorLi, YM-
dc.creatorXu, L-
dc.creatorTang, W-
dc.creatorLam, FL-
dc.creatorLo, WH-
dc.creatorYu, WY-
dc.creatorFan, Q-
dc.creatorChan, ASC-
dc.date.accessioned2015-06-23T09:11:22Z-
dc.date.available2015-06-23T09:11:22Z-
dc.identifier.issn0957-4166-
dc.identifier.urihttp://hdl.handle.net/10397/30862-
dc.language.isoenen_US
dc.publisherPergamon Pressen_US
dc.titleAsymmetric hydrogenation of quinolines with recyclable and air-stable iridium catalyst systemsen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage2625-
dc.identifier.epage2631-
dc.identifier.volume18-
dc.identifier.issue22-
dc.identifier.doi10.1016/j.tetasy.2007.10.034-
dcterms.abstractThe iridium complex-catalyzed asymmetric hydrogenation of quinolines in a DMPEG/hexane biphasic system was studied. Catalysts with C-2-symmetric ligands such as Xyl-P-Phos, Cl-MeO-BIPHEP, SYNPHOS, and DiluorPhos are highly effective for this type of reaction. Most of the catalysts tested can be retained in DMPEG (M-n = 500), and the asymmetric hydrogenation of various quinoline substrates can be carried out in DMPEG/hexane biphasic system with up to 92% ee. The catalysts and the products can be separated via simple phase separation, and the reactivity/stereoselectivity of the catalysts can be retained for at least three reaction cycles.-
dcterms.bibliographicCitationTetrahedron : asymmetry, 2007, v. 18, no. 22, p. 2625-2631-
dcterms.isPartOfTetrahedron : asymmetry-
dcterms.issued2007-
dc.identifier.isiWOS:000251923900004-
dc.identifier.eissn1362-511X-
dc.identifier.rosgroupidr39778-
dc.description.ros2007-2008 > Academic research: refereed > Publication in refereed journal-
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