Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/30834
Title: Highly air- and water-stable fluorinated ferrocenylphosphine-aminophosphine ligands and their applications in asymmetric hydrogenations
Authors: Li, X
Jia, X
Xu, L
Kok, SHL
Yip, CW
Chan, ASC
Keywords: Air-stable ligands
Asymmetric hydrogenation
Enamides
Ferrocenylphosphine-aminophosphine ligands
Rhodium
Issue Date: 2005
Publisher: Wiley-VCH
Source: Advanced synthesis & catalysis, 2005, v. 347, no. 15, p. 1904-1908 How to cite?
Journal: Advanced synthesis & catalysis 
Abstract: Air- and water-stable fluorinated ferrocenylphosphine-aminophosphine ligands have been synthesized and applied to the Rh-catalyzed asymmetric hydrogenation of enamides and α-dehydroamino acid derivatives. These reactions afforded the corresponding products in good to excellent ees (up to 99.7% ee) and nearly quantitative yields. The combination of the remarkable air- and water-stability with excellent catalytic performance makes these catalysts excellent choices for practical applications.
URI: http://hdl.handle.net/10397/30834
ISSN: 1615-4150
EISSN: 1615-4169
DOI: 10.1002/adsc.200505241
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