Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/30014
Title: Rhodium-catalyzed cross-coupling reaction of arylboronates and diazoesters and tandem alkylation reaction for the synthesis of quaternary alpha,alpha-heterodiaryl carboxylic esters
Authors: Tsoi, YT
Zhou, Z
Yu, WY 
Issue Date: 2011
Publisher: American Chemical Society
Source: Organic letters, 2011, v. 13, no. 19, p. 5370-5373 How to cite?
Journal: Organic letters 
Abstract: A rhodium-catalyzed one-pot three-component coupling reaction was developed for the synthesis of quaternary alpha,alpha-heterodiaryl carboxylic esters. This reaction involves cross-coupling of the arylrhodium(I) complexes with alpha-aryldiazoacetates to form oxa-pi-allylrhodium complexes. With KOfBu and alkyl halides, tandem alkylation of the allyl complex occurs to form a quaternary stereocenter at the carbenic carbon.
URI: http://hdl.handle.net/10397/30014
ISSN: 1523-7060
EISSN: 1523-7052
DOI: 10.1021/ol2022577
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