Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/29612
Title: Single-, double- and triple-stranded helical metal complexes of chiral tetradentate pyridyl-thiazole ligands : stereoselective synthesis, spectroscopic properties and structural characterization
Authors: Tsang, CS
Yee, CC
Yiu, SM
Wong, WT 
Kwong, HL
Keywords: Chiral tetradentate ligand
Double-stranded
Helical metal complex
Pyridyl-thiazole
Triple-stranded
Issue Date: 2014
Source: Polyhedron, 2014, v. 83, p. 167-177 How to cite?
Journal: Polyhedron 
Abstract: With a series of chiral pyridine-based tetradentate pyridyl-thiazole ligands L, three types of binuclear helical metal complexes were synthesized. They were the Re(I) single-stranded complexes of formula [Re2(L)(CO)6Br2], the Ag(I) double-stranded complexes of formula [Ag2(L)2](ClO4)2 and the Cu(II) triple-stranded complex of formula [Cu2(L)3](ClO4)4. Each type of them has been characterized using CD spectroscopy and if possible 1H NMR spectroscopy. Three single crystal structures, one from each type, have been determined.
URI: http://hdl.handle.net/10397/29612
ISSN: 0277-5387
DOI: 10.1016/j.poly.2014.05.062
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