Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/29394
Title: Asymmetric hydroalkynylation of norbornadienes promoted by chiral iridium catalysts
Authors: Fan, BM
Yang, QJ
Hu, J
Fan, CL
Li, SF
Yu, L
Huang, C
Tsang, WW
Kwong, FY 
Keywords: alkynes
asymmetric catalysis
C-H activation
iridium
synthetic methods
Issue Date: 2012
Publisher: Wiley-VCH
Source: Angewandte chemie international edition, 2012, v. 51, no. 31, p. 7821-7824 How to cite?
Journal: Angewandte chemie international edition 
Abstract: Across bonds: The first successful iridium-catalyzed asymmetric hydroalkynylation of nonpolar alkenes with good to excellent enantioselectivity is described (see scheme; cod=1,5-cyclooctadiene, DCE=1,2-dichloroethane). This catalytic system exhibits good functional group compatibility as NH2, OH, Br, F, and SiMe3 groups remain intact during the reaction.
URI: http://hdl.handle.net/10397/29394
ISSN: 1433-7851
EISSN: 1521-3773
DOI: 10.1002/anie.201203107
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