Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/29294
Title: Coupling reaction of Phenylacetylene with OsHn(PPh 3)(2,6-(PPh2CH2)2C6H 3) (n = 1, 3)
Authors: Wen, TB
Zhou, ZY
Jia, G
Issue Date: 2003
Publisher: American Chemical Society
Source: Organometallics, 2003, v. 22, no. 24, p. 4947-4951 How to cite?
Journal: Organometallics 
Abstract: Treatment of OsCl(=C=CHPh)(PPh3)(PCP) with thallium acetate produces the vinylidene complex Os(O2CCH3)(=C=CHPh)(PCP). Treatment of OsCl(PPh3)(PCP) with NaH in wet THF produces a mixture of the monohydride OsH(PPh3)(PCP) and the trihyhride OsH 3(PPh3)(PCP). The latter complexes react with phenylacetylene to give Os(C≡CPh)(=C= CHPh)(PPh3)(l-(CHPh=C)-2, 6-(PPh2CH2)2C6H3).
URI: http://hdl.handle.net/10397/29294
ISSN: 0276-7333
EISSN: 1520-6041
DOI: 10.1021/om034141w
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