Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/28726
Title: Synthesis and characterization of a metallabenzyne
Authors: Bin, WT
Zhou, ZY
Jia, G
Keywords: Alkyne complexes
Carbyne complexes
Metallacycles
Osmium
Vinylidene complexes
Issue Date: 2001
Publisher: Wiley-VCH
Source: Angewandte chemie international edition, 2001, v. 40, no. 10, p. 1951-1954 How to cite?
Journal: Angewandte chemie international edition 
Abstract: Although many metallabenzenes are known, complex 1 appears to be the first well-characterized example of a metallabenzyne. It has been synthesized by treatment if [OsCl 2(PPh 3) 3] with an excess of HC≡CSiMe 3 in wet benzene. The structure of the novel complex 1 was confirmed by single crystal X-ray diffraction, which showed the six-membered ring to be essentially planar with a maximum deviation form the least-squares plane of 0.047 Å.
URI: http://hdl.handle.net/10397/28726
ISSN: 1433-7851
EISSN: 1521-3773
DOI: 10.1002/1521-3773(20010518)40:10<1951
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