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Title: Synthesis, characterization, crystal structure and thermal decomposition of the dimmer complex [Ni(TSSB)(Phen)(H2O)]·4H2O
Authors: Zhang, SH
Jiang, YM
Xing, M
Zhou, ZY
Keywords: Crystal structure
Nickel compound
Taurine-salicylaldehyde Schiff base
Issue Date: 2005
Publisher: 该刊
Source: 无机化学学报 (Chinese journal of inorganic chemistry), 2005, v. 21, no. 9, p. 1392-1396 How to cite?
Journal: 无机化学学报 (Chinese journal of inorganic chemistry) 
Abstract: The new compound, [Ni (TSSB) (Phen) (H2O)]·4H 2O (TSSB =Taurine Salicylic Schiff Base, phen=0-Phenanthroline) has been synthesized and characterized by IR, elemental analysis and X-ray diffraction. The compound crystal data: triclinic, space group P1, a=1.0497(2), b=1.1225(2), c=2.3843(4) nm, α=87.676(3)°, β= 82.957(3)°, γ=62.924(3)°; V=2.4823(7) nm3, Z=4; Dc=1.488 g·cm-3, μ=0.920 mm-1, F(000)=1 160, Goof=1.032, (Δρ)max=899 e·nm-3, (Δρ) min=-624 e·nm-3. The compound is a dimmer. In the complex, two Ni(II) were coordinated by three oxygen atoms and three nitrogen atoms while the O atoms of Ac- groups did not coordinate. The Ni(II) formed a distorted octahedron geometry. The compound is an three dimensional net connecting with hydrogen bonding. CCDC: 275474. The TG-IR of the complex was analyzed. The kinetics of the thermal decomposition reaction of the complex was studied under a non isothermal condition by TG-IR. TG and DTG curves indicate that the complex decomposed in four stages: (Equation Presented).
ISSN: 1001-4861
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