Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/25339
Title: trans-(1S,2S)-1-substituted-2-(N,N-dialkylamino)-1-indanol derivatives as chiral ligands in the catalytic enantioselective addition of diethylzinc to aldehydes
Authors: Xu, Q
Yang, H
Pan, X
Chan, ASC
Issue Date: 2002
Publisher: Pergamon Press
Source: Tetrahedron : asymmetry, 2002, v. 13, no. 9, p. 945-951 How to cite?
Journal: Tetrahedron : asymmetry 
Abstract: A series of optically active trans-(1S,2S)-1-substituted-2-(N,N-dialkylamino)-1-indanol derivatives 1-6 were synthesized and applied in the catalytic enantioselective addition of diethylzinc to aldehydes. The enantiomeric purity of the addition products increased considerably with increasing bulk of the substituents both on the nitrogen atom and the hydroxy-bearing carbon atom of the ligands. sec-Alcohols were obtained in good yields with enantiomeric excesses up to 93.1%.
URI: http://hdl.handle.net/10397/25339
ISSN: 0957-4166
EISSN: 1362-511X
DOI: 10.1016/S0957-4166(02)00183-0
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