Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/25187
Title: Novel manganese complex as an efficient catalyst for the isobutyraldehyde-mediated epoxidation of cyclic alkenes with dioxygen
Authors: Qi, JY
Li, YM
Zhou, ZY
Che, CM
Yeung, CH
Chan, ASC
Keywords: Cyclic alkene
Dioxygen
Epoxidation
Manganese complex
N,O ligands
Issue Date: 2005
Publisher: Wiley-VCH
Source: Advanced synthesis & catalysis, 2005, v. 347, no. 1, p. 45-49 How to cite?
Journal: Advanced synthesis & catalysis 
Abstract: The highly efficient oxidation of cyclic alkenes was realized using a novel manganese complex as catalyst and molecular oxygen as oxidant in the presence of isobutyraldehyde. The reaction of 2-pyridinecarboxylic acid with p-toluidine gave the corresponding amide in good yield. A manganese complex bearing this ligand was highly active in isobutyraldehyde-mediated epoxidation of cyclic alkenes using molecular oxygen as oxidant, and up to and over 99.9% conversion of the substrate and 99% yield of the epoxide were obtained for the epoxidation of norbornylene.
URI: http://hdl.handle.net/10397/25187
ISSN: 1615-4150
EISSN: 1615-4169
DOI: 10.1002/adsc.200404224
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