Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/23153
Title: A perchlorate-promoted electrochemically induced nitride coupling reaction
Authors: Chan, PH
Chen, SP
Yeung, KW
Cheung, KC
Hong, S
Sun, SG
Wong, KY 
Keywords: Electrochemically induced nitride coupling
Osmium nitride
Issue Date: 2005
Publisher: Elsevier
Source: Electrochemistry communications, 2005, v. 7, no. 12, p. 1244-1248 How to cite?
Journal: Electrochemistry communications 
Abstract: The osmium nitride complex [OsVI(NH3) 4N]3+ undergoes a one-electron reduction in acetonitrile to give [OsV(N)(NH3)4]2+, which further reacts by nitride coupling to give the μ-dinitrogen osmium complex [(CH3CN)(NH3)4OsII(N 2)OsII(NH3)4(CH3CN)] 4+. The formation of the μ-dinitrogen osmium complex is promoted by the presence of perchlorate anion, which causes the deposition of [(CH 3CN)(NH3)4OsII(N2)Os II(NH3)4(CH3CN)](ClO 4)4 on the electrode surface upon repetitive voltammetric scans.
URI: http://hdl.handle.net/10397/23153
ISSN: 1388-2481
EISSN: 1873-1902
DOI: 10.1016/j.elecom.2005.08.028
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