Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/22970
Title: Rhodium-catalyzed asymmetric hydrogenation with aminophosphine ligands derived from 1,1 '-binaphthyl-2,2 '-diamine
Authors: Guo, RW
Li, XS
Wu, J
Kwok, WH
Chen, J
Choi, MCK
Chan, ASC
Keywords: Aminophosphine ligand
Asymmetric hydrogenation
Rhodium
Amino acid derivatives
Issue Date: 2002
Publisher: Pergamon Press
Source: Tetrahedron letters, 2002, v. 43, no. 38, p. 6803-6806 How to cite?
Journal: Tetrahedron letters 
Abstract: Chiral ligands 2,2'-bis(dicyclohexylphosphinoamino)-1,1'-binaphthyI and 2,2'-bis[bis(3,5-dimethylphenyl)phosphinoamino]- 1,1'-binaphthyl were synthesized by reacting 1,1'-binaphthyl-2,2'-diamine with dicyclohexylchlorophosphine and bis(3,5-dimethylphenyl)chlorophosphine, respectively. Application of these ligands to the Rh-catalyzed asymmetric hydrogenation of a variety of amidoacrylic acids and esters provided chiral amino acid derivatives with excellent enantioselectivities (up to 99% e.e. and quantitative yields).
URI: http://hdl.handle.net/10397/22970
ISSN: 0040-4039
EISSN: 1873-3581
DOI: 10.1016/S0040-4039(02)01510-1
Appears in Collections:Journal/Magazine Article

Access
View full-text via PolyU eLinks SFX Query
Show full item record

SCOPUSTM   
Citations

31
Last Week
0
Last month
Citations as of Oct 15, 2017

WEB OF SCIENCETM
Citations

26
Last Week
0
Last month
0
Citations as of Oct 15, 2017

Page view(s)

40
Last Week
0
Last month
Checked on Oct 15, 2017

Google ScholarTM

Check

Altmetric



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.