Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/22641
Title: Recent advances in developing new axially chiral phosphine ligands for asymmetric catalysis
Authors: Li, YM
Kwong, FY 
Yu, WY 
Chan, ASC
Keywords: Asymmetric catalysis
Chiral ligands
Phosphines
Issue Date: 2007
Publisher: Elsevier
Source: Coordination chemistry reviews, 2007, v. 251, no. 17-20, p. 2119-2144 How to cite?
Journal: Coordination chemistry reviews 
Abstract: This review article illustrates the concept and approach for designing new C-2-symmetric chelating atropisomeric chiral phosphines containing g heterocyclic scaffolds. The versatility in structural modification is highlighted, and that it offers an effective avenue to access chiral ligands of diverse electronic and steric properties for optimization in various catalytic asymmetric transformations. In this article, the uses of atropisomeric chiral phosphines in some asymmetric transformations such as hydrogenation and alkyl-/arylation reactions will be discussed with reference to updated literature findings as well as the author's original research.
URI: http://hdl.handle.net/10397/22641
ISSN: 0010-8545
EISSN: 1873-3840
DOI: 10.1016/j.ccr.2007.07.020
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