Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/20113
Title: Progress towards the total synthesis of scytonemin A : asymmetric synthesis of (2S,3R,4R)-4-hydroxy-3-methylproline
Authors: Wang, L
Liu, J
Zhang, H
Xu, Z
Ye, T 
Keywords: Scytonemin A
Cyclopeptide
Substituted proline
Amino acids
Asymmetric synthesis
Issue Date: 2010
Publisher: Georg Thieme Verlag
Source: Synlett, 2010, no. 4, p. 563-566 How to cite?
Journal: Synlett 
Abstract: During the total synthesis of the novel cyclopeptide scytonemin A, the fragment containing two (2S,3R,4R)-4-hydroxy-3-methylproline units was successfully prepared. Two approaches leading to (2S,3R,4R)-4-hydroxy-3-methylproline have been explored. They involve the following key transformations: asymmetric crotylation, Sharpless epoxidation-subsequent epoxide opening, intramolecular amidomercuration-oxidation.
URI: http://hdl.handle.net/10397/20113
ISSN: 0936-5214
EISSN: 1437-2096
DOI: 10.1055/s-0029-1219208
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