Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/20086
Title: Palladium-(S,pR)-FerroNPS-catalyzed asymmetric allylic etherification : electronic effect of nonconjugated substituents on benzylic alcohols on enantioselectivity
Authors: Lam, FL
Au-Yeung, TTL
Kwong, FY 
Zhou, Z
Wong, KY 
Chan, ASC
Keywords: Asymmetric catalysis
Electronic effects
Etherification
P,S ligands
Palladium
Issue Date: 2008
Publisher: Wiley-VCH
Source: Angewandte chemie international edition, 2008, v. 47, no. 7, p. 1280-1283 How to cite?
Journal: Angewandte chemie international edition 
Abstract: (Chemical Equation Presented) An enantioselective C-O bond-forming reaction proceeds well under palladium catalysis with newly developed N-P,S ligands with a ferrocene motif (see scheme). Nonconjugated substituents on the benzylic alcohol substrate lead to an increase in enantioselectivity with increasing electron-donating ability in the title reaction with racemic 1,3-diphenyl-2-propenyl acetate. Cy = cyclohexyl.
URI: http://hdl.handle.net/10397/20086
ISSN: 1433-7851
EISSN: 1521-3773
DOI: 10.1002/anie.200703955
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