Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/19435
Title: Ligand C-C bond cleavage on ruthenium : observation of a reversible ruthenium(V)-imido/ruthenium(II)-amine couple and X-ray crystal structure of [ru(bpy)2(NH=CMe2)2](PF6) 2 (bpy = 2,2′-bipyridine)
Authors: Wong, KY 
Che, CM
Li, CK
Chiu, WH
Zhou, ZY
Mak, TCW
Issue Date: 1992
Source: Journal of the Chemical Society, Chemical Communications, 1992, no. 10, p. 754-756 How to cite?
Journal: Journal of the Chemical Society, Chemical Communications 
Abstract: A reversible three-proton three-electron couple has been observed for the electrochemical oxidation of cis-[Ru(bpy)2(L)]2+ (L = 2,3-dimethyl-2,3-diaminobutane) in aqueous acidic solution; controlled-potential electrochemical oxidation of cis-[Ru(bpy)2(L)]2+ led to C-C bond cleavage in L and formation of cis-[Ru(bpy)2(NH=CMe 2)2]2+ whose structure has been determined by X-ray crystallography.
URI: http://hdl.handle.net/10397/19435
ISSN: 0022-4936
DOI: 10.1039/C39920000754
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