Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/19107
Title: Palladium-catalyzed decarboxylative arylation of C-H bonds by aryl acylperoxides
Authors: Yu, WY 
Sit, WN
Zhou, Z
Chan, AS
Issue Date: 2009
Publisher: American Chemical Society
Source: Organic letters, 2009, v. 11, no. 15, p. 3174-3177 How to cite?
Journal: Organic letters 
Abstract: A Pd(OAc) 2-catalyzed protocol for decarboxylative arylation of aromatic C-H bond was developed using aryl acylperoxides as inexpensive aryl sources. Substrates containing pyridyl, oxime, and oxazoline groups undergo effectively ortho-selective C-H arylation with excellent functional group tolerance. This arylation should begin by directing-group-assisted cyclopalladation, followed by the reaction of the palladacycle with aryl radicals generated in situ by thermal decomposition of the peroxides.
URI: http://hdl.handle.net/10397/19107
ISSN: 1523-7060
EISSN: 1523-7052
DOI: 10.1021/ol900756g
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