Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/19006
Title: Simultaneous estimation of VOCs diffusion and partition coefficients in building materials via inverse analysis
Authors: Li, F
Niu, J 
Keywords: Diffusion coefficient
Indoor air
Inverse method
Mass transport
Parameter estimation
VOCs
Issue Date: 2005
Publisher: Pergamon Press
Source: Building and environment, 2005, v. 40, no. 10, p. 1366-1374 How to cite?
Journal: Building and environment 
Abstract: An analytic model describing the one-dimensional transient VOC diffusion in the building material slab was selected. An inverse analysis was applied to estimate the volatile organic compounds (VOCs) constant diffusion coefficient (D) and partition coefficient (K) in the building material. The present parameter estimation problem was solved with Levenberg-Marquardt's method of minimization of the ordinary least-squares norm. The effects of the number and the time step of measurements, errors involved in the initial concentration data in the building material, random errors involved in the measured VOCs concentration data in the chamber air and errors involved in the calculation of the mean convective mass transfer coefficient on the accuracy of estimates were studied. The first two factors were found to have significant effects on the accuracy of the estimates, while the effect of the third factor was insignificant. The results also indicate that D is insensitive to the errors involved in the mean convective mass transfer coefficient. The present study would be useful for obtaining material properties and helpful for designing and improving experiments.
URI: http://hdl.handle.net/10397/19006
ISSN: 0360-1323
EISSN: 1873-684X
DOI: 10.1016/j.buildenv.2004.10.016
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