Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/16847
Title: Synthesis and structure of anti-configuration complex [Cu(tssb)(2)]center dot 2[(H3O)Cl]center dot 4H(2)O
Authors: Zhang, SH
Jiang, YM
Liu, Z
Zhou, ZY
Keywords: Copper complex
Taurine-salicylaldehyde Schiff base
Crystal structure
Anti-configuration
Issue Date: 2004
Publisher: 中國學術期刊(光盤版)電子雜誌社
Source: 结构化学 (Chinese journal of structural chemistry), 2004, v. 23, no. 8, p. 882-885 How to cite?
Journal: 结构化学 (Chinese journal of structural chemistry) 
Abstract: The title complex [Cu(tssb)(2)](.)2[(H3O)Cl](.)4H(2)O (C18H34Cl2CuN2O14S2) (tssb = taurine salicylaldehyde Schiff base) has been synthesized by the reaction of taurine salicylaldehyde Schiff base (tssb) and copper acetate in water-ethanol. Its single-crystal structure was determined by X-ray diffraction method. The crystal structure belongs to triclinic, space group P (1) over bar with a = 0.7407(1), b = 1.3329(3), c = 1.5736(3) nm, a = 103.800(4), beta = 95.030(4), gamma = 104.416(4)degrees, M-r = 701.06, V = 1.4433(5) nm(3), Z = 2, D-c = 1.613 g/cm(3), mu = 1.153 mm(-1) and F(000) = 726. The compound is an infinitely expanding three-dimensional network connected with hydrogen bonds. The Cu(II) atom is coordinated by two nitrogen and two oxygen atoms to form a distorted planar coordination compound which adopts anti-configuration because two sulfonic acid groups are positioned diagonally on a plane.
URI: http://hdl.handle.net/10397/16847
ISSN: 0254-5861
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