Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/16724
Title: Facile preparation of chiral 1,3-diols via stereoselective transfer hydrogenation of 1,3-diones
Authors: Chen, YC
Deng, JG
Wu, TF
Cui, X
Jiang, YZ
Choi, MCK
Chan, ASC
Keywords: Asymmetric transfer hydrogenation
Ruthenium complex
Chiral 1,3-diols
Issue Date: 2001
Publisher: Science Press
Source: Chinese journal of chemistry, 2001, v. 19, no. 8, p. 807-810 How to cite?
Journal: Chinese Journal of Chemistry 
Abstract: Asymmetric reduction of 1,3-diones catalyzed by (S,S)-TsD-PEN-Ru (II) complex in a mixture of formic acid-triethylamine proceeded with a substrate/catalyst molar ratio of 100 to give (S, S)-1,3-diols with excellent diastereomeric (98.6% de) and enantiomeric purities (> 99% ce). Other C-2-symmetric diols were also obtained in almost quantitative yields with high diastereomeric (80.0%-84.2% de) and enantiomeric purities(> 99% ee).
URI: http://hdl.handle.net/10397/16724
ISSN: 1001-604X
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