Please use this identifier to cite or link to this item:
Title: Luminescent property of a supramolecular silver (I)-Thiolate complex bases on secondary Ag-S interactions and hydrogen
Authors: Su, WP
Hong, MC
Cao, R
Weng, JB
Zhou, ZY
Chan, SCA
Keywords: Silver(I)-thiolate
Crystal structure
Luminescence property
Issue Date: 2001
Publisher: Science Press
Source: Chinese journal of chemistry, 2001, v. 19, no. 9, p. 817-821 How to cite?
Journal: Chinese Journal of Chemistry 
Abstract: The supramolecular silver(l)-thiolate complex [Ag(mu (2)-SC4N2H4)(2)(SCN)](n) has been prepared from the reaction of AgSCN and pyrimidine-2-thiol in DMT. X-ray diffraction analysis shows that the supramolecular structure exhibits one-dimensional chain through the secondary Ag S Interactions and the chains are further linked by strong hydrogen bonds to form a three dimensional network. The luminescence effect from the silver-centered state of S --> Ag LMCT in solid state is different from that in solution due to the secondary Ag-S interactions.
ISSN: 1001-604X
Appears in Collections:Journal/Magazine Article

View full-text via PolyU eLinks SFX Query
Show full item record

Page view(s)

Last Week
Last month
Citations as of Dec 17, 2018

Google ScholarTM


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.