Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/15922
Title: Luminescent property of a supramolecular silver (I)-Thiolate complex bases on secondary Ag-S interactions and hydrogen
Authors: Su, WP
Hong, MC
Cao, R
Weng, JB
Zhou, ZY
Chan, SCA
Keywords: Silver(I)-thiolate
Crystal structure
Luminescence property
Issue Date: 2001
Publisher: Science Press
Source: Chinese journal of chemistry, 2001, v. 19, no. 9, p. 817-821 How to cite?
Journal: Chinese Journal of Chemistry 
Abstract: The supramolecular silver(l)-thiolate complex [Ag(mu (2)-SC4N2H4)(2)(SCN)](n) has been prepared from the reaction of AgSCN and pyrimidine-2-thiol in DMT. X-ray diffraction analysis shows that the supramolecular structure exhibits one-dimensional chain through the secondary Ag S Interactions and the chains are further linked by strong hydrogen bonds to form a three dimensional network. The luminescence effect from the silver-centered state of S --> Ag LMCT in solid state is different from that in solution due to the secondary Ag-S interactions.
URI: http://hdl.handle.net/10397/15922
ISSN: 1001-604X
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