Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/15583
Title: Highly efficient rhodium/monodentate phosphoramidite catalyst and its application in the enantioselective hydrogenation of enamides and alpha-dehydroamino acid derivatives
Authors: Jia, X
Li, XS
Xu, LJ
Shi, Q
Yao, XS
Chan, ASC
Issue Date: 2003
Publisher: American Chemical Society
Source: Journal of organic chemistry, 2003, v. 68, no. 11, p. 4539-4541 How to cite?
Journal: Journal of organic chemistry 
Abstract: An easily prepared and highly efficient monodentate phosphoramidite ligand derived from BINOL, (S)2,2'-O,O-(1,1'-binaphthyl)-dioxo-N,N-diethylphospholidine, was examined in the hydrogenation of both enamides and alpha-dehydroamino acid derivatives. The catalyst provided remarkably high enantioselectivities (up to 99.6% ee for enamides and >99.9% ee for alpha-dehydroamino acid derivatives).
URI: http://hdl.handle.net/10397/15583
ISSN: 0022-3263
EISSN: 1520-6904
DOI: 10.1021/jo026869c
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