Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/15179
Title: Intermolecular enantioselective dearomatization reaction of £]-naphthol using meso-aziridine : a bifunctional in situ generated magnesium catalyst
Authors: Yang, D
Wang, L
Han, F
Li, D
Zhao, D
Wang, R
Keywords: Arenes
Aromaticity
Intermolecular reactions
Ligand design
Magnesium
Issue Date: 2015
Publisher: Wiley-VCH Verlag
Source: Angewandte chemie - International edition, 2015, v. 54, no. 7, p. 2185-2189 How to cite?
Journal: Angewandte Chemie - International Edition 
Abstract: A direct, facile, and highly diastereo- and enantio-selective dearomatization reaction of £]-naphthol derivatives with aziridines has been developed for the first time. A newly designed Box-OH ligand was employed for an in situ generated magnesium catalyst and proved to be efficient. The corresponding dearomatization product was transformed into a polycyclic scaffold and polyhydroxylated compound. 1H NMR studies revealed the activation mode of the dearomatization process of £]-naphthols, and a clear positive nonlinear effect was observed in the reaction, and provides insight into the coordination environment around the MgII center and the possible active species.
URI: http://hdl.handle.net/10397/15179
ISSN: 1433-7851
DOI: 10.1002/anie.201410257
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