Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/14558
Title: Highly enantioselective hydrogenation of alpha-dehydroamino acids by rhodium complex with H-8-MonoPhos
Authors: Zeng, Q
Liu, H
Cui, X
Mi, AQ
Jiang, YZ
Li, XS
Choi, MCK
Chan, ASC
Issue Date: 2002
Publisher: Pergamon Press
Source: Tetrahedron : asymmetry, 2002, v. 13, no. 2, p. 115-117 How to cite?
Journal: Tetrahedron : asymmetry 
Abstract: H-8-MonoPhos, a new stable and easily prepared monodentate phosphoramidite ligand, has been synthesized from H-8-BINOL. The ligand showed extremely highly enantioselectivity of higher than 99.9% e.e. in the asymmetric Rh-catalyzed hydrogenation of alpha-dehydroamino acids. Our study further supports the new concept that there is no gap in efficiency and enantioselectivity between monodentate and chelating ligands for asymmetric catalysis.
URI: http://hdl.handle.net/10397/14558
ISSN: 0957-4166
EISSN: 1362-511X
DOI: 10.1016/S0957-4166(02)00096-4
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