Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/14211
Title: Indirect catalytic epoxidation with hydrogen peroxide electrogenerated in ionic liquids
Authors: Ho, KP
Wong, KY 
Chan, TH 
Keywords: Electrogeneration
Hydrogen peroxide
Ionic liquids
Manganese/bicarbonate-catalyzed epoxidation
Oxygen reduction
Issue Date: 2006
Publisher: Pergamon Press
Source: Tetrahedron, 2006, v. 62, no. 28, p. 6650-6658 How to cite?
Journal: Tetrahedron 
Abstract: Hydrogen peroxide was generated in room temperature ionic liquids by electrolysis, which was then used for the epoxidation of lipophilic alkenes under a carbon dioxide-saturated environment and in the presence of catalytic amount of manganese salt. 13C NMR showed that the active peroxymonocarbonate (HCO4-) was generated from the mixture of H2O2, CO2, and water in the ionic liquids. Most lipophilic alkenes were selectively epoxidized within 4-5 h. The ionic liquids can be recovered and reused without any deterioration in the performance.
URI: http://hdl.handle.net/10397/14211
ISSN: 0040-4020
DOI: 10.1016/j.tet.2005.12.075
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