Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/13944
Title: Suzuki- Miyaura coupling of aryl tosylates catalyzed by an array of indolyl phosphine- palladium catalysts
Authors: So, CM
Lau, CP
Chan, ASC
Kwong, FY 
Issue Date: 2008
Publisher: American Chemical Society
Source: The journal of organic chemistry, 2008, v. 73, no. 19, p. 7731-7734 How to cite?
Journal: Journal of organic chemistry 
Abstract: A family of indolyl phosphine ligands was applied to Suzuki−Miyaura cross-coupling of aryl tosylates. Catalyst loading can be reduced to 0.2 mol % for coupling of nonactivated aryl tosylate. A challenging example for room temperature coupling is realized. The scope of this highly active Pd/L2 system can be extended to other boron nucleophiles, including trifluoroborate salts and boronate esters. The ligand structural comparisons toward the reactivity in tosylate couplings are also described.
URI: http://hdl.handle.net/10397/13944
ISSN: 0022-3263
EISSN: 1520-6904
DOI: 10.1021/jo8014819
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