Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/12747
Title: Ionic-liquid-supported synthesis : a novel liquid-phase strategy for organic synthesis
Authors: Miao, W
Chan, TH
Issue Date: 2006
Source: Accounts of chemical research, 2006, v. 39, no. 12, p. 897-908 How to cite?
Journal: Accounts of Chemical Research 
Abstract: Soluble ionic liquids have recently been used as supports for catalyst/reagent immobilization and synthesis in homogeneous solution phase. The wide range of ionic liquid supports available makes their use as supports compatible with most common chemistries. The solubility properties of these ionic liquid supports can be tuned by the variation of cations and anions to make them phase separate from less polar organic solvents and aqueous media. The ionic-liquid-supported species can therefore be purified from the reaction mixture by simple washings. Ionic-liquid-supported catalysts and reagents have been prepared and used, and they are easily recovered and reused. Parallel and combinatorial libraries of small molecules have been synthesized. Ionic-liquid-supported synthesis (ILSS) has been applied to the preparation of oligopeptides and oligosaccharides. The comparison of ILSS with solid-phase synthesis, soluble-polymer-supported synthesis, and fluorous phase synthesis has been highlighted where applicable.
URI: http://hdl.handle.net/10397/12747
ISSN: 0001-4842
DOI: 10.1021/ar030252f
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