Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/12680
Title: Synthesis and crystal structures of lanthanide complexes with foliage growth regulator : phenoxyalkanoic acid
Authors: Shi, SM
Chen, ZF
Liu, YC
Mao, L
Liang, H
Zhou, ZY
Keywords: 2,4-Dichlorophenoxyacetic acid
Crystal structures
Europium
Lanthanide complexes
Lanthanum
Neodymium
Phenoxyacetic acid
Issue Date: 2008
Publisher: Taylor & Francis Ltd
Source: Journal of coordination chemistry, 2008, v. 61, no. 17, p. 2725-2734 How to cite?
Journal: Journal of Coordination Chemistry 
Abstract: Reactions of Ln(ClO4)3·6H2O (Ln=La(III), Eu(III), Nd(III)), 1,10-phenanthroline (phen) and phenoxyacetic acid (PA) or 2,4- dichlorophenoxyacetic acid (2,4-D) yield [La(PA)2 (phen)2]2(ClO4)2 (1), [Eu(2,4-D)2(phen)2]2(ClO4)2 (2) and [Nd(2,4-D)3(C2H5OH)]n (3). Compounds 1-3 are characterized by elemental analyses, IR, UV-Vis, ESI-MS spectra and TGA. 1 is also characterized by 1H and 13C NMR. Single crystal X-ray diffraction analyses reveal that 1 and 2 are binuclear, and 3 has a one-dimensional polymeric structure. The La(III), Eu(III) and Nd(III) are nine-coordinate with a distorted tricapped trigonal-prism geometry.
URI: http://hdl.handle.net/10397/12680
DOI: 10.1080/00958970801961455
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