Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/11595
DC FieldValueLanguage
dc.contributorDepartment of Applied Biology and Chemical Technology-
dc.creatorZhang, X-
dc.creatorGong, L-
dc.creatorMi, A-
dc.creatorCui, X-
dc.creatorJiang, Y-
dc.creatorChoi, CKM-
dc.creatorChan, SCA-
dc.date.accessioned2015-06-23T09:12:24Z-
dc.date.available2015-06-23T09:12:24Z-
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10397/11595-
dc.language.isoenen_US
dc.publisherPergamon Pressen_US
dc.subjectAminoalcoholsen_US
dc.subjectDiethylzinc additionen_US
dc.subjectIminesen_US
dc.subjectSuzuki couplingen_US
dc.titleEnantioselective addition of diethylzinc to N-diphenylphosphinoylimines employing N,N-dialkyl-1,2-diphenyl-2-aminoethanols as chiral ligandsen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage6369-
dc.identifier.epage6372-
dc.identifier.volume42-
dc.identifier.issue36-
dc.identifier.doi10.1016/S0040-4039(01)01273-4-
dcterms.abstractBy fine-tuning the substituents on the nitrogen of (1S,2R) and (1R,2S)-1,2-diphenyl-2-aminoethanols, a chiral ligand 2b was obtained, which showed excellent enantioselectivity, with up to 94% e.e, for the asymmetric addition of diethylzinc to N-diphenylphosphinoylimines 1. In one example, the optically active amide 3c was converted into a new amine 5 with 98% e.e. by a reaction sequence involving Suzuki coupling and hydrolysis without racemization.-
dcterms.bibliographicCitationTetrahedron letters, 2001, v. 42, no. 36, p. 6369-6372-
dcterms.isPartOfTetrahedron letters-
dcterms.issued2001-
dc.identifier.isiWOS:000170636400037-
dc.identifier.scopus2-s2.0-0035801909-
dc.identifier.eissn1873-3581-
dc.identifier.rosgroupidr07044-
dc.description.ros2001-2002 > Academic research: refereed > Publication in refereed journal-
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