Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/11569
Title: Reaction enthalpies and activation energies of two important reactions in flame suppression by CF3Br
Authors: Lee, EPF
Dyke, JM
Chau, FT
Chow, WK 
Mok, DKW 
Issue Date: 2003
Source: Chemical physics letters, 2003, v. 376, no. 3-4, p. 465-474
Abstract: Reaction enthalpies and activation energies of the reactions: CF 3Br→CF3+Br and CF3Br+H→CF 3+HBr, were calculated at near state-of-the-art level, and compared with available experimental values and values employed in kinetic modelling of flame suppression. An ab initio strategy for evaluating reliable reaction enthalpies and activation energies for reactions considered in kinetic modelling of fire inhibition is recommended.
Publisher: Elsevier
Journal: Chemical physics letters 
ISSN: 0009-2614
DOI: 10.1016/S0009-2614(03)01005-4
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